Pd錯体と有機塩基の協奏的触媒作用
同一固体表面にPd錯体とアミンを固定した触媒の協奏効果によって、アリル化反応の大幅な加速を実現しました。Pd基準の触媒回転数は最高で106,000に達しました。
[if gte vml 1]><v:group id="_x0000_s1026" style='position:absolute; left:0;text-align:left;margin-left:102.4pt;margin-top:124pt;width:296.6pt; height:202.95pt;z-index:251658240' coordorigin="2198,2705" coordsize="5932,4059"> <v:shapetype id="_x0000_t75" coordsize="21600,21600" o:spt="75" o:preferrelative="t" path="m@4@5l@4@11@9@11@9@5xe" filled="f" stroked="f"> <v:stroke joinstyle="miter"></v:stroke> <v:formulas> <v:f eqn="if lineDrawn pixelLineWidth 0"></v:f> <v:f eqn="sum @0 1 0"></v:f> <v:f eqn="sum 0 0 @1"></v:f> <v:f eqn="prod @2 1 2"></v:f> <v:f eqn="prod @3 21600 pixelWidth"></v:f> <v:f eqn="prod @3 21600 pixelHeight"></v:f> <v:f eqn="sum @0 0 1"></v:f> <v:f eqn="prod @6 1 2"></v:f> <v:f eqn="prod @7 21600 pixelWidth"></v:f> <v:f eqn="sum @8 21600 0"></v:f> <v:f eqn="prod @7 21600 pixelHeight"></v:f> <v:f eqn="sum @10 21600 0"></v:f> </v:formulas> <v:path o:extrusionok="f" gradientshapeok="t" o:connecttype="rect"></v:path> <o:lock v:ext="edit" aspectratio="t"></o:lock> </v:shapetype><v:shape id="図_x0020_1" o:spid="_x0000_s1027" type="#_x0000_t75" style='position:absolute;left:3134;top:4163;width:3916;height:2374; visibility:visible'> <v:imagedata src="file:///C:\Users\Motokura\AppData\Local\Temp\msohtmlclip1\01\clip_image001.emz" o:title=""></v:imagedata> </v:shape><v:rect id="正方形_x002f_長方形_x0020_41" o:spid="_x0000_s1028" style='position:absolute; left:2987;top:3954;width:4158;height:2810;visibility:visible;v-text-anchor:middle' o:gfxdata="UEsDBBQABgAIAAAAIQC2gziS/gAAAOEBAAATAAAAW0NvbnRlbnRfVHlwZXNdLnhtbJSRQU7DMBBF 90jcwfIWJU67QAgl6YK0S0CoHGBkTxKLZGx5TGhvj5O2G0SRWNoz/78nu9wcxkFMGNg6quQqL6RA 0s5Y6ir5vt9lD1JwBDIwOMJKHpHlpr69KfdHjyxSmriSfYz+USnWPY7AufNIadK6MEJMx9ApD/oD OlTrorhX2lFEilmcO2RdNtjC5xDF9pCuTyYBB5bi6bQ4syoJ3g9WQ0ymaiLzg5KdCXlKLjvcW893 SUOqXwnz5DrgnHtJTxOsQfEKIT7DmDSUCaxw7Rqn8787ZsmRM9e2VmPeBN4uqYvTtW7jvijg9N/y JsXecLq0q+WD6m8AAAD//wMAUEsDBBQABgAIAAAAIQA4/SH/1gAAAJQBAAALAAAAX3JlbHMvLnJl bHOkkMFqwzAMhu+DvYPRfXGawxijTi+j0GvpHsDYimMaW0Yy2fr2M4PBMnrbUb/Q94l/f/hMi1qR JVI2sOt6UJgd+ZiDgffL8ekFlFSbvV0oo4EbChzGx4f9GRdb25HMsYhqlCwG5lrLq9biZkxWOiqY 22YiTra2kYMu1l1tQD30/bPm3wwYN0x18gb45AdQl1tp5j/sFB2T0FQ7R0nTNEV3j6o9feQzro1i OWA14Fm+Q8a1a8+Bvu/d/dMb2JY5uiPbhG/ktn4cqGU/er3pcvwCAAD//wMAUEsDBBQABgAIAAAA IQBwxOf1NwIAADwEAAAOAAAAZHJzL2Uyb0RvYy54bWysU8GO0zAQvSPxD5bvNEmbdkvUdCWoygXB igVxnjpOYuHYlu027YfAB8CZM+LA57ASf8HYCe0CN0QOzoxn5s28mfHq+thJcuDWCa1Kmk1SSrhi uhKqKemb19tHS0qcB1WB1IqX9MQdvV4/fLDqTcGnutWy4pYgiHJFb0raem+KJHGs5R24iTZcobHW tgOPqm2SykKP6J1Mpmm6SHptK2M1487h7WYw0nXEr2vO/Mu6dtwTWVKszcfTxnMXzmS9gqKxYFrB xjLgH6roQChMeobagAeyt+IvqE4wq52u/YTpLtF1LRiPHJBNlv7B5rYFwyMXbI4z5za5/wfLXhxu LBFVSfMpJQo6nNHd5093H75+//Yx+fH+yyCRPAut6o0rMOLW3NhRcygG3sfaduGPjMgxtvd0bi8/ esLwcrrI00U2o4ShLbta5vksD6jJJdxY559x3ZEglNTi/GJb4fDc+cH1l0vIpvRWSIn3UEhFekR9 nM5xzAxwlWoJHsXOIDmnGkpANrijzNsI6bQUVQgP0c42u6fSkgPgnuTbZfZkMzi1UPHhdp7iN5Y7 usfSf8MJxW3AtUNINI0hUoU8PK4kcgmK3ntub9uqJzu5t68A65ynS0xCKhHYz5bZoOC+Tq9CejQN JLykxGr/Vvg2LknodYAM+c88dhLYu6F90rQwkoswl1aid6RxLiZq9+pMwtCHMQdpp6sTbgwo1mqs K3QzgAUTrmgMHp9TeAP39eh1efTrnwAAAP//AwBQSwMEFAAGAAgAAAAhABfrJHzeAAAACAEAAA8A AABkcnMvZG93bnJldi54bWxMj0FPwkAQhe8m/IfNkHiTbbEYqd0SxBCPBDTE49Id24bubOluS/n3 jie9zcx7efO9bDXaRgzY+dqRgngWgUAqnKmpVPD5sX14BuGDJqMbR6jghh5W+eQu06lxV9rjcAil 4BDyqVZQhdCmUvqiQqv9zLVIrH27zurAa1dK0+krh9tGzqPoSVpdE3+odIubCovzobcKjm/J1/H9 9WaG8lL08eNOnjfbnVL303H9AiLgGP7M8IvP6JAz08n1ZLxoFHCRwNd5sgTBchIvuMmJh2ixBJln 8n+B/AcAAP//AwBQSwECLQAUAAYACAAAACEAtoM4kv4AAADhAQAAEwAAAAAAAAAAAAAAAAAAAAAA W0NvbnRlbnRfVHlwZXNdLnhtbFBLAQItABQABgAIAAAAIQA4/SH/1gAAAJQBAAALAAAAAAAAAAAA AAAAAC8BAABfcmVscy8ucmVsc1BLAQItABQABgAIAAAAIQBwxOf1NwIAADwEAAAOAAAAAAAAAAAA AAAAAC4CAABkcnMvZTJvRG9jLnhtbFBLAQItABQABgAIAAAAIQAX6yR83gAAAAgBAAAPAAAAAAAA AAAAAAAAAJEEAABkcnMvZG93bnJldi54bWxQSwUGAAAAAAQABADzAAAAnAUAAAAA " filled="f" strokecolor="#385d8a" strokeweight="1.5pt"> <v:shadow on="t" color="black" opacity="26214f" origin="-.5,-.5" offset=".74836mm,.74836mm"></v:shadow> </v:rect><v:shape id="図_x0020_2" o:spid="_x0000_s1029" type="#_x0000_t75" style='position:absolute;left:2198;top:2705;width:5932;height:1113; visibility:visible'> <v:imagedata src="file:///C:\Users\Motokura\AppData\Local\Temp\msohtmlclip1\01\clip_image002.emz" o:title=""></v:imagedata> </v:shape></v:group><![endif][if !vml][endif]