

長谷川 慎吾
(E-mail: hasegawa-shingo-rg [at] ynu.ac.jp)
横浜国立大学 大学院工学研究院
助教
学位:博士(理学)(2022年3月 東京大学)
職歴
学術論文
受賞歴
2022年4月-現在 横浜国立大学 大学院工学研究院 助教
2025年10月-2029年3月 科学技術振興機構(JST) さきがけ研究者 (兼任)
2019年4⽉-2022年3月 ⽇本学術振興会特別研究員(DC1) (東京⼤学 佃達哉 研究室)
[33] Shingo Hasegawa, Shunta Tokutake, Koji Harano, Ken Motokura, "Pd Nanoparticles Decorated by Oxidized Ru Clusters for Efficient C–H/C–H Coupling of Arenes", ACS Catalysis, 2025, 15, 487-493.
[32] Shingo Hasegawa, Kosuke Soga, Ken Motokura, “Silica-Immobilized Cyclic Urea Catalyst for the Reduction of Carboxylic Acids to Alcohols”, JACS Au 2025, 5, 1914–1921.
[31] Shingo Hasegawa, Shion Nakamura, Koji Harano, Ken Motokura, "Synergistic Catalysis of PtRu Oxide Cluster for Arene C–H Bond Activation", Applied Catalysis A: General, 2025, 708, 120531.
[30] Kenta Suzuki, Shingo Hasegawa, Ryota Osuga, Kiyotaka Nakajima, Ken Motokura, "Remote Activation Catalysis: Interparticle Hydrogen Spillover-Assisted Cumene Synthesis from Propane and Benzene", Small, 2025, 2408226.
[29] Xiuling Guo, Chao Feng, Zihao Yang, Shingo Hasegawa, Ken Motokura, Yong Yang, "Local Symmetry-Broken Single Pd Atoms Induced by Doping Ag Sites for Selective Electrocatalytic Semihydrogenation of Alkynes", ACS Nano, 2025, 19, 2788-2798.
[28] Takuya Shiroshita, Shingo Hasegawa, Yusuke Tanimura, Azusa Kikuchi, Ken Motokura, "Recycling of Waste Silicon Wafers for Semihydrogenation of Alkynes", ACS Sustainable Chemistry & Engineering 2025, 13, 8331–8341.
[27] Ken Motokura, Yurino Sasaki, Yusuke Tanimura, Takuya Shiroshita, Shingo Hasegawa, Kousuke Arata, Ryosuke Takemura, Kazuo Namba, Yuichi Manaka, "Conversion of CO2 in Exhaust Gas to Formic Acid and Formamides with Wasted Silicon Recovered from End-of-Life Solar Panels", ACS Sustainable Resource Management 2025, 2, 1220–1227.
[26] Yuanjun Zhao, Xin Zhou, Shingo Hasegawa, Ken Motokura, Dmitry Gorbunov, Yong Yang, "Efficient and stable heterogeneous Pd-catalyzed regioselective Anti-Markovnikov carbonylative coupling of alkenes with amines", Chemical Engineering Journal 2025, 515, 163493.
[25] Mariko Honda, Shunichi Sakai, Shingo Hasegawa, Wang-Jae Chun, Ken Motokura, “Silica-Immobilized Pd–Amine Catalysts for Suzuki–Miyaura Coupling with Catalytic Amounts of Base”, Langmuir 2025, 41, 10605–10613.
[24] Zhaozhan Wang, Zihao Yang, Yifan Liu, Shingo Hasegawa, Ken Motokura, Shaoping Kuang, Yong Yang, “Constructing single-atom Rh sites for selective hydroformylation of 1,3-butadiene to adipic aldehyde”, Chemical Engineering Journal, 2025, 505, 159698.
[23] Kenta Suzuki, Shingo Hasegawa, Ken Motokura, "Direct alkylation of benzene with propane promoted by a hydrotalcite-supported Pt–Fe and solid acid catalyst system", Catalysis Today 2025, 460, 115448.
[22] Mariko Honda, Shingo Hasegawa, Ken Motokura, "Oxygen‐Accelerated Suzuki–Miyaura Coupling Reaction Without Stoichiometric Base Addition", ChemistrySelect 2025, 10, e02285.
[21] Jincheng Wu, Yusuke Tanimura, Danyang Liu, Shingo Hasegawa, Kousuke Arata, Ryosuke Takemura, Kazuo Namba, Ken Motokura, "Conversion of CO2 to Formic Acid Using Silicon Sludge as a Reducing Agent", Journal of the Japan Petroleum Institute, 2025, 68, 170–176.
[20] Shingo Hasegawa, Koji Harano, Ken Motokura, "RhRu Bimetallic Oxide Cluster Catalysts for Cross-Dehydrogenative Coupling of Arenes and Carboxylic Acids",
Journal of the American Chemical Society 2024, 146, 19059–19069.
[19] Shunichi Sakai, Shingo Hasegawa, Siming Ding, Ryota Osuga, Kiyotaka Nakajima, Shinji Tanaka, Wang-Jae Chun, Ken Motokura, "Low Temperature N-Allylation of Allylic Alcohols via Synergistic Pd/Cu Catalysis: A Silica-Supported Dual Metal Complex Strategy", ACS Catalysis 2024, 14, 4835–4846.
[18] Shingo Hasegawa, Ken Motokura, "Design Strategy of Metal Nanoparticle Catalysis for C–H Bond Activation Reactions", ChemCatChem 2024, 16, e202301531.
[17] Yuanjun Zhao, Xin Zhou, Zihao Yang, Shingo Hasegawa, Ken Motokura, Zhaozhan Wang, Bo Yu, Xiaolin Shi, Guoqiang Xu, Xin Ding, Yong Yang,
"Regioselective hydroformylation of allyl alcohol catalyzed by phosphine-stabilized single-atom Rh sites", Chemical Engineering Journal, 2024, 502, 157733.
[16] Satoshi Misaki, Moe Takabatake, Shingo Hasegawa, Yuichi Manaka, Wang-Jae Chun, Ken Motokura, "Effect of Zeolites on the Alkylation of Aromatics with Alkanes using a Pd Nanoparticle/Solid Acid Cooperative Catalytic System" Green Carbon, 2024, 2, 282-290.
[15] Ken Motokura, Satoshi Misaki, Shingo Hasegawa, Moe Takabatake, Yusuke Tanimura, Yuichi Manaka, Wang-Jae Chun, "Effects of the Support Preparation Conditions on the Direct Alkylation of Toluene Catalyzed by Hydrotalcite-Supported Pd Nanoparticles and Solid Acid" Journal of the Japan Petroleum Institute, 2024, 67, 186-194.
[14] Ken Motokura, Yukina Nakamura, Moe Takabatake, Kenta Suzuki, Shingo Hasegawa, "Direct Alkylation of Benzene with Branched Alkanes using Solid Acids: Unexpected Product Selectivity Based on the Tertiary Carbon Position", Catal. Today 2024, 425, 114363.
[13] Shingo Hasegawa, Keisuke Nakamura, Kosuke Soga, Kei Usui, Yuichi Manaka, Ken Motokura, "Concerted Hydrosilylation Catalysis by Silica-Immobilized Cyclic Carbonates and Surface Silanols", JACS Au 2023, 3, 2692-2697.
[12] Satoshi Misaki, Hiroko Ariga-Miwa, Takashi U. Ito, Takefumi Yoshida, Shingo Hasegawa, Yukina Nakamura, Shunta Tokutake, Moe Takabatake, Koichi Shimomura, Wang-Jae Chun, Yuichi Manaka, Ken Motokura, "Pd Nanoparticles on the Outer Surface of Microporous Aluminosilicates for the Direct Alkylation of Benzenes using Alkanes", ACS Catal. 2023, 13, 12281-12287.
[11] Ken Motokura, Kyosuke Gomi, Kyogo Maeda, Shunichi Sakai, Shingo Hasegawa, Wang-Jae Chun, Yuichi Manaka, "Silica-Supported Cu Complex Catalysis for Chan-Evans-Lam Coupling Reaction between Aniline and Phenylboronic Acid", J. Jpn. Petrol. Inst. 2023, 66, 171-179.
[10] Ken Motokura, Ayaka Mizuno, Shingo Hasegawa, Masayuki Nambo, Moe Takabatake, Kenta Suzuki, Yuichi Manaka, Yohei Uemura, Shuntaro Tsubaki, Wang-Jae Chun, "In Situ Formation of Ru-Sn Bimetallic Particles for Non-Oxidative Coupling of Methane", J. Phys. Chem. C 2023, 127, 15185-15194.
[9] Zhaozhan Wang, Shingo Hasegawa, Ken Motokura, Shaoping Kuang, Yong Yang, "A Single-Atom Pd Catalyst Anchored on a Porous Organic Polymer for Highly Efficient Telomerization of 1,3-Butadiene with Methanol", Ind. Eng. Chem. Res. 2023, 62, 3151-3156.
[8] Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, Jun Kikkawa, and Tatsuya Tsukuda, "Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster", ACS Nano 2022, 16, 16932-16940.
[7] Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda, “Polymer-Stabilized Au38 Cluster: Atomically Precise Synthesis by Digestive Ripening and Characterization of Atomic Structure and Oxidation Catalysis”, ACS Catal. 2022, 12, 6550-6558.
[6] Shingo Hasegawa, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda, “New Magic Au24 Cluster Stabilized by PVP: Selective Formation, Atomic Structure, and Oxidation Catalysis”, JACS Au 2021, 1, 660-668.
[5] Shingo Hasegawa and Tatsuya Tsukuda, “Exploring Novel Catalysis Using Polymer-Stabilized Metal Clusters”, Bull. Chem. Soc. Jpn. 2021, 94, 1036-1044.
[4] Atsushi Matsuo, Shingo Hasegawa, Shinjiro Takano, and Tatsuya Tsukuda, “Electron-Rich Gold Clusters Stabilized by Polyvinylpyridines as Robust and Active Oxidation Catalysts”, Langmuir 2020, 36, 7844-7849.
[3] Shinjiro Takano, Shingo Hasegawa, Megumi Suyama, and Tatsuya Tsukuda, “Hydride Doping of Chemically Modified Gold-Based Superatoms”, Acc. Chem. Res. 2018, 51, 3074-3083.
[2] Shingo Hasegawa, Shinjiro Takano, Seiji Yamazoe, and Tatsuya Tsukuda, “Prominent Hydrogenation Catalysis of a PVP-Stabilized Au34 Superatom Provided by Doping a Single Rh Atom”, Chem. Commun. 2018, 54, 5915-5918.
[1] Shun Hayashi, Ryo Ishida, Shingo Hasegawa, Seiji Yamazoe, and Tatsuya Tsukuda, “Doping a Single Palladium Atom into Gold Superatoms Stabilized by PVP: Emergence of Hydrogenation Catalysis”, Top. Catal. 2018, 61, 136-14.
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